Introduction to Strategies for Organic Synthesis
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Introduction to Strategies for Organic Synthesis
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eBay-Artikelnr.:197239118035
Artikelmerkmale
- Artikelzustand
- Release Year
- 2018
- Book Title
- Introduction to Strategies for Organic Synthesis
- ISBN
- 9781119347248
Über dieses Produkt
Product Identifiers
Publisher
Wiley & Sons, Incorporated, John
ISBN-10
1119347246
ISBN-13
9781119347248
eBay Product ID (ePID)
239722294
Product Key Features
Number of Pages
432 Pages
Publication Name
Introduction to Strategies for Organic Synthesis
Language
English
Subject
Chemistry / Physical & Theoretical, Chemistry / Organic, Chemistry / General
Publication Year
2018
Type
Textbook
Subject Area
Science
Format
Trade Paperback
Dimensions
Item Height
0.8 in
Item Weight
23.2 Oz
Item Length
8.9 in
Item Width
5.9 in
Additional Product Features
Edition Number
2
Intended Audience
Scholarly & Professional
LCCN
2017-046041
Dewey Edition
23
Illustrated
Yes
Dewey Decimal
547.2
Table Of Content
Preface xix Acknowlegments xxi CHAPTER 1 Synthetic Toolbox 1: Retrosynthesis and Protective Groups 1 1.1 Retrosynthetic Analysis 3 1.2 Protective Groups 11 CHAPTER 1 Problems Protective Groups 19 CHAPTER 2 Synthetic Toolbox 2: Overview of Organic Transformations 21 2.1 Nucleophiles and Electrophiles 23 2.2 Oxidation and Reduction Reactions 27 CHAPTER 2 Problems Nucleophiles, Electrophiles, and Redox 41 CHAPTER 3 Synthesis of Monofunctional Target Molecules (1-FG TMs) 45 3.1 Synthesis of Alcohols (ROH) and Phenols (ArOH) 47 3.2 Synthesis of Alkyl (RX) and Aryl Halides (ArX) 61 3.3 Synthesis of Ethers (ROR') 67 3.4 Synthesis of Thiols (RSH) and Thioethers (RSR´) 73 3.5 Synthesis of Amines (RNH2) and Anilines (ArNH2) 77 3.6 Synthesis of Alkenes (R2C¨TCR2) 85 3.7 Synthesis of Alkynes (RC≡CR') 93 3.8 Synthesis of Alkanes (RH) 97 3.9 Synthesis of Aldehydes and Ketones (RCHO, R2C¨TO) 105 3.10 Synthesis of Carboxylic Acids (RCO2H) 117 3.11 Synthesis of Carboxylic Acid Derivatives 125 CHAPTER 3 Problems 1-FG TMs 139 CHAPTER 4 Synthesis of Target Molecules with Two Functional Groups (2-FG TMs) 143 4.1 Synthesis of β©\Hydroxy Carbonyls and α,β©\Unsaturated Carbonyls 145 4.2 More Enolate Reactions: Synthesis of 1,3©\Dicarbonyls, 1,5©\Dicarbonyls, and Cyclohexenones 157 4.3 "Illogical" 2©\Group Disconnections: Umpolung (Polarity Reversal) 171 CHAPTER 4 Problems 2-FG TMs 183 CHAPTER 5 Synthesis of Aromatic Target Molecules 187 5.1 Electrophilic Aromatic Substitution (ArH + E+ → ArE) 189 5.2 Synthesis of Aromatic TMs via Diazonium Salts (ArN2 + + Nu: → ArNu) 201 5.3 Nucleophilic Aromatic Substitution (ArX + Nu: → ArNu) 205 CHAPTER 5 Problems Aromatic TMs 209 CHAPTER 6 Synthesis of Compounds Containing Rings 211 6.1 Synthesis of Cyclopropanes 213 6.2 Synthesis of Cyclobutanes 215 6.3 Synthesis of Five©\Membered Rings (Radical Cyclization Reactions) 217 6.4 Synthesis of Six©\Membered Rings (Diels-Alder Reaction) 221 CHAPTER 6 Problems Cyclic TMs 231 CHAPTER 7 Predicting and Controlling Stereochemistry 235 7.1 Reactions that Form Racemates 237 7.2 SN2 Mechanism: Backside Attack 243 7.3 Elimination Mechanisms 245 7.4 Additions to Alkenes and Alkynes 247 7.5 Additions to Carbonyls 251 7.6 Additions to Enolates: Aldol Stereochemistry 257 7.7 Enantioselectivity and Asymmetric Syntheses 261 CHAPTER 7 Problems Stereochemistry 269 CHAPTER 8 Transition Metal-Mediated Carbon-Carbon Bond Formation 273 8.1 Transition Metal Coordination Complexes 275 8.2 Organometallic Reaction Mechanisms 283 8.3 Carbonylation and Decarbonylation 291 8.4 (ArX + Alkene → Ar©\Alkene) 295 8.5 Palladium©\Catalyzed Cross©\Coupling Reactions (RX + R'M → R©\R') 297 8.6 Olefin Metathesis Reactions 303 8.7 Retrosynthesis: Disconnections Based on Metal-Mediated Reactions 307 CHAPTER 8 Problems Transition Metal-Mediated Synthesis 309 SOLUTIONS TO PROBLEMS 313 Index 389
Synopsis
Bridging the Gap Between Organic Chemistry Fundamentals and Advanced Synthesis Problems Introduction to Strategies of Organic Synthesis bridges the knowledge gap between sophomore-level organic chemistry and senior-level or graduate-level synthesis to help students more easily adjust to a synthetic chemistry mindset., Bridging the Gap Between Organic Chemistry Fundamentals and Advanced Synthesis Problems Introduction to Strategies of Organic Synthesis bridges the knowledge gap between sophomore-level organic chemistry and senior-level or graduate-level synthesis to help students more easily adjust to a synthetic chemistry mindset. Beginning with a thorough review of reagents, functional groups, and their reactions, this book prepares students to progress into advanced synthetic strategies. Major reactions are presented from a mechanistic perspective and then again from a synthetic chemist's point of view to help students shift their thought patterns and teach them how to imagine the series of reactions needed to reach a desired target molecule. Success in organic synthesis requires not only familiarity with common reagents and functional group interconversions, but also a deep understanding of functional group behavior and reactivity. This book provides clear explanations of such reactivities and explicitly teaches students how to make logical disconnections of a target molecule. This new Second Edition of Introduction to Strategies for Organic Synthesis Reviews fundamental organic chemistry concepts including functional group transformations, reagents, stereochemistry, and mechanisms Explores advanced topics including protective groups, synthetic equivalents, and transition-metal mediated coupling reactions Helps students envision forward reactions and backwards disconnections as a matter of routine Gives students confidence in performing retrosynthetic analyses of target molecules Includes fully-worked examples, literature-based problems, and over 450 chapter problems with detailed solutions Provides clear explanations in easy-to-follow, student-friendly language Focuses on the strategies of organic synthesis rather than a catalogue of reactions and modern reagents The prospect of organic synthesis can be daunting at the outset, but this book serves as a useful stepping stone to refresh existing knowledge of organic chemistry while introducing the general strategies of synthesis. Useful as both a textbook and a bench reference, this text provides value to graduate and advanced undergraduate students alike., Bridging the Gap Between Organic Chemistry Fundamentals and Advanced Synthesis Problems Introduction to Strategies of Organic Synthesis bridges the knowledge gap between sophomore-level organic chemistry and senior-level or graduate-level synthesis to help students more easily adjust to a synthetic chemistry mindset. Beginning with a thorough review of reagents, functional groups, and their reactions, this book prepares students to progress into advanced synthetic strategies. Major reactions are presented from a mechanistic perspective and then again from a synthetic chemist's point of view to help students shift their thought patterns and teach them how to imagine the series of reactions needed to reach a desired target molecule. Success in organic synthesis requires not only familiarity with common reagents and functional group interconversions, but also a deep understanding of functional group behavior and reactivity. This book provides clear explanations of such reactivities and explicitly teaches students how to make logical disconnections of a target molecule. This new Second Edition of Introduction to Strategies for Organic Synthesis : Reviews fundamental organic chemistry concepts including functional group transformations, reagents, stereochemistry, and mechanisms Explores advanced topics including protective groups, synthetic equivalents, and transition-metal mediated coupling reactions Helps students envision forward reactions and backwards disconnections as a matter of routine Gives students confidence in performing retrosynthetic analyses of target molecules Includes fully-worked examples, literature-based problems, and over 450 chapter problems with detailed solutions Provides clear explanations in easy-to-follow, student-friendly language Focuses on the strategies of organic synthesis rather than a catalogue of reactions and modern reagents The prospect of organic synthesis can be daunting at the outset, but this book serves as a useful stepping stone to refresh existing knowledge of organic chemistry while introducing the general strategies of synthesis. Useful as both a textbook and a bench reference, this text provides value to graduate and advanced undergraduate students alike., BRIDGING THE GAP BETWEEN ORGANIC CHEMISTRY FUNDAMENTALS AND ADVANCED SYNTHESIS PROBLEMS Introduction to Strategies for Organic Synthesis bridges the knowledge gap between sophomore-level organic chemistry and senior-level or graduate-level synthesis to help students more easily adjust to a synthetic chemistry mindset. Beginning with a thorough review of reagents, functional groups, and their reactions, this book prepares students to progress into advanced synthetic strategies. Major reactions are presented from a mechanistic perspective and then again from a synthetic chemists point of view to help students shift their thought patterns and teach them how to imagine the series of reactions needed to reach a desired target molecule. Success in organic synthesis requires not only familiarity with common reagents and functional group interconversions, but also a deep understanding of functional group behavior and reactivity. This book provides clear explanations of such reactivities and explicitly teaches students how to make logical disconnections of a target molecule. This new Second Edition of Introduction to Strategies for Organic Synthesis : Reviews fundamental organic chemistry concepts including functional group transformations, reagents, stereochemistry, and mechanisms Explores advanced topics including protective groups, synthetic equivalents, and transition-metal mediated coupling reactions Helps students envision forward reactions and backwards disconnections as a matter of routine Gives students confidence in performing retrosynthetic analyses of target molecules Includes fully-worked examples, literature-based problems, and over 450 chapter problems with detailed solutions Provides clear explanations in easy-to-follow, student-friendly language Focuses on the strategies of organic synthesis rather than a catalog of reactions and modern reagents The prospect of organic synthesis can be daunting at the outset, but this book serves as a useful stepping stone to refresh existing knowledge of organic chemistry while introducing the general strategies of synthesis. Useful as both a textbook and a bench reference, this text provides value to graduate and advanced undergraduate students alike.
LC Classification Number
QD262.S812 2018
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